Boyu Peng, Ke Cao* Albert Ho Yuen Lau, Ming Chen, Yang Lu* and Paddy K. L. Chan
Crystallized Monolayer Semiconductor for Ohmic Contact Resistance, High Intrinsic Gain, and High Current Density
Adv. Mater. 2020, 32, 2002281
DOI:10.1002/adma.202002281
Department of Mechanical Engineering, The University of Hong Kong, Pokfulam Road (HK)
*Department of Mechanical Engineering, City University of Hong Kong, Kowloon (HK)
Abstract: The contact resistance limits the downscaling and operating range of organic field-effect transistors (OFETs). Access resistance through multilayers of molecules and the nonideal metal/semiconductor interface are two major bottlenecks preventing the lowering of the contact resistance. In this work, monolayer (1L) organic crystals and nondestructive electrodes are utilized to overcome the abovementioned challenges. High intrinsic mobility of 12.5 cm2 V−1 s−1 and Ohmic contact resistance of 40 Ω cm are achieved. Unlike the thermionic emission in common Schottky contacts, the carriers are pre- dominantly injected by field emission. The 1L-OFETs can operate linearly from VDS = −1 V to VDS as small as −0.1 mV. Thanks to the good pinch-off behavior brought by the monolayer semiconductor, the 1L-OFETs show high intrinsic gain at the saturation regime. At a high bias load, a maximum current density of 4.2 µA µm−1 is achieved by the only molecular layer as the active channel, with a current saturation effect being observed. In addition to the low contact resistance and high-resolution lithography, it is suggested that the thermal management of high-mobility OFETs will be the next major challenge in achieving high-speed densely integrated flexible electronics.
Fig: a) Schematic charge accumulation and b) output curves of short-channel OFETs. c) Schematic charge accumulation and d) output curves of source-gated transistors. e) Schematic charge accumulation and f) output curves of 1L-OFETs.
Acknowledgements: The authors gratefully acknowledge the support from the General Research Fund (GRF) under Grant Nos. HKU 17264016 and HKU 17204517, University of Hong Kong Seed Funding Grant Nos. 201711159068 and 201611159208. The authors appreciate Prof. Xin Cheng and Xin Zhuang from Southern University of Science and Technology for their support on e-beam lithography. The authors also thank Dr. Hagen Klauk and James W. Borchert for the fruitful discussions and suggestions.
